Methodological comparison for quantitative analysis of fossil and recently derived carbon in mine soils with high content of aliphatic kerogen     

《Organic Geochemistry》2015

In mine soil, quantification of soil organic carbon (OC) derived recently from biomass decomposition is complicated by the presence of fossil (geogenic) C derived from coal, oil shale, or similar material in the overburden. The only reliable method for such measurement is ¹⁴C analysis (i.e. radiocarbon dating) using instrumentation such as accelerator mass spectrometry, which is too expensive for routine laboratory analysis. We tested two previously used and two new methods for recent C quantification and compared them with ¹⁴C AMS radiocarbon dating as a reference using a set of soil samples (n = 14) from Sokolov, Czech Republic: (i) ¹³C isotope ratio composition, (ii) cross polarization magic angle spinning ¹³C nuclear magnetic resonance (CPMAS ¹³C NMR) spectroscopy, (iii) near infrared spectroscopy (NIRS) coupled with partial least squares regression and (iv) Rock–Eval pyrolysis. Conventional methods for OC determination (dry combustion, wet dichromate oxidation, loss-on-ignition) were also compared to quantify any bias connected with their use. All the methods provided acceptable recent carbon estimates in the presence of mostly aliphatic fossil C from kerogen. However, the most accurate predictions were obtained with two approaches using Rock–Eval pyrolysis parameters as predictors, namely (i) S₂ curve components and (ii) oxygen index (OI). The S₂ curve approach is based on the lower thermal stability of recent vs. fossil organic matter. The OI approach corresponded well with ¹³C NMR spectra, which showed that samples rich in recent C were richer in carboxyl C and O-alkyl C. These two methods showed the greatest potential as routine methods for recent C quantification.  相似文献   

咸化湖盆白云岩碳氧同位素特征及古环境意义:以柴西地区始新统下干柴沟组为例   总被引：4，自引：0，他引：4  

袁剑英  黄成刚  曹正林  李智勇  万传治  徐丽  潘星  吴丽荣 《地球化学》2015,44(3)

近年来,柴西地区始新统致密碳酸盐岩中的油气勘探获得了重要进展,其中白云岩为最优质的储集岩。系统的岩石学、矿物学和地球化学特征研究表明,该套白云岩主要为泥晶结构,白云石晶间孔广泛发育,孔径多小于1μm。泥晶白云岩的δ13CPDB值变化范围为-4.5‰~0.2‰,平均值为-2.4‰,相对于典型湖相碳酸盐岩偏负,反映了周缘辫状三角洲供给富含轻碳的地表水在一定程度上改变了白云岩的碳同位素组成,且湖水中的溶解碳部分来源于有机质氧化解体产生的CO2,通过改变湖水中溶解碳的碳同位素组成从而间接影响了湖相白云岩的碳同位素组成。泥晶白云岩的δ18OPDB值变化范围为-6.1‰~0.4‰,平均值为-2.6‰,相对于典型湖相碳酸盐岩偏正,明显受咸化湖沉积环境影响。碳氧同位素相关关系投点图及其计算出的盐度、温度数据反映了泥晶白云岩是在准同生阶段、半开放-半封闭的咸化环境下、于水/沉积物界面附近由方解石交代而成的低温白云岩,这类准同生交代成因白云岩在区域上分布较广,且孔径极小的白云石晶间孔抗压实能力强,这一重要发现无论是平面展布上还是纵向深度上均开拓了柴达木盆地致密油勘探的新领域。  相似文献   

Historical influences on the current provision of multiple ecosystem services     

《Global Environmental Change》2015

Ecosystem service provision varies temporally in response to natural and human-induced factors, yet research in this field is dominated by analyses that ignore the time-lags and feedbacks that occur within socio-ecological systems. The implications of this have been unstudied, but are central to understanding how service delivery will alter due to future land-use/cover change. Urban areas are expanding faster than any other land-use, making cities ideal study systems for examining such legacy effects. We assess the extent to which present-day provision of a suite of eight ecosystem services, quantified using field-gathered data, is explained by current and historical (stretching back 150 years) landcover. Five services (above-ground carbon density, recreational use, bird species richness, bird density, and a metric of recreation experience quality (continuity with the past) were more strongly determined by past landcover. Time-lags ranged from 20 (bird species richness and density) to over 100 years (above-ground carbon density). Historical landcover, therefore, can have a strong influence on current service provision. By ignoring such time-lags, we risk drawing incorrect conclusions regarding how the distribution and quality of some ecosystem services may alter in response to land-use/cover change. Although such a finding adds to the complexity of predicting future scenarios, ecologists may find that they can link the biodiversity conservation agenda to the preservation of cultural heritage, and that certain courses of action provide win-win outcomes across multiple environmental and cultural goods.  相似文献   

Payments for Ecosystem Services (PES) in the face of external biophysical stressors     

《Global Environmental Change》2015

Economic instruments such as Payments for Ecosystem Services (PES) schemes are increasingly promoted to protect ecosystems (and their associated ecosystem services) that are threatened by processes of local and global change. Biophysical stressors external to a PES site, such as forest fires, pollution, sea level rise, and ocean acidification, may undermine ecosystem stability and sustained ecosystem service provision, yet their threats and impacts are difficult to account for within PES scheme design. We present a typology of external biophysical stressors, characterizing them in terms of stressor origin, spatial domain and temporal scale. We further analyse how external stressors can potentially impinge on key PES parameters, as they (1) threaten ecosystem service provision, additionality and permanence, (2) add challenges to the identification of PES providers and beneficiaries, and (3) add complexity and costs to PES mechanism design. Effective PES implementation under external stressors requires greater emphasis on the evaluation and mitigation of external stressors, and further instruments that can accommodate associated risks and uncertainties. A greater understanding of external stressors will increase our capacity to design multi-scale instruments to conserve important ecosystems in times of environmental change.  相似文献   

The burial of biogenic silica,organic carbon and organic nitrogen in the sediments of the East China Sea     

Wang  Lisha  Zhang  Chuansong  Shi  Xiaoyong 《中国海洋大学学报(英文版)》2015,14(3):464-470

We sampled the sediments of the East China Sea during 2005 and 2006, and analysed the contents of the biogenic mat-ters: biogenic silica, organic carbon, and organic nitrogen. From the surface distribu...  相似文献   

滦河流域碳、水循环和能量平衡遥感综合试验总体设计     

阎广建  赵天杰  穆西晗  闻建光  庞勇  贾立  张永光  陈德清  姚崇斌  曹志宇  雷永荟  姬大彬  陈良富  柳钦火  吕利清  陈镜明  施建成 《遥感学报》2021,25(4):856-870

始于20世纪80年代的系列大型遥感试验开始系统研究地表物质和能量交换过程,对遥感与地球系统科学研究的结合起到重要作用,但是尚无综合利用多源遥感数据解决碳、水、能量循环问题的有效方案。遥感科学国家重点实验室于滦河上游地区组织开展基础性、多学科、多尺度的"碳、水循环和能量平衡遥感综合试验"。本次试验面向地球系统科学对遥感观测的最新要求,以遥感如何服务地—气过程研究为关键科学问题,开展星—机—地多尺度遥感综合观测和地面测量,论证中国自主设计的碳、水、能量相关卫星的技术指标,基于大场景真实结构模拟和多尺度综合观测构建虚拟遥感试验场,验证全波段遥感机理模型和复杂地表辐射传输机理。核心试验区位于地势较为平坦的闪电河流域和地形复杂的小滦河流域。闪电河流域主要地类为农田和草地,开展的试验以水循环和能量平衡遥感综合观测为主。小滦河流域主要地类为森林和草地,以碳循环遥感综合观测为主。两个试验区都开展了系统性的多架次飞行试验,并同步开展地面全波段、主被动协同观测。特别设计了一次长达165 km的大跨度飞行试验,横跨两个试验区,包含了地表类型和海拔高度的逐渐过渡。从2017年的预实验开始,整个试验为期5年。基于科学目标驱动、开放、协作、共享的原则,本次试验吸引了10个大型国家科研项目,4个卫星计划团队,19家单位200人次参加,是中国主导的又一次具有明确科学目标的大型多学科交叉遥感综合试验。  相似文献   

河流泥沙输移过程中矿物风化的碳汇效应初探——以长江干流为例     

张信宝  罗景城  王小国  唐家良  彭韬  朱波 《地质学报》2023,97(7):2378-2385

本文首先提出了河流泥沙输移过程中泥沙中的钙镁矿物溶蚀消耗水体中的CO2并具有碳汇功能的观点。基于前人长江干流从源头到入海口和支流2003~2007年期间4次河流悬移质泥沙的化学元素组成和矿物组成资料,分析悬移质中CaO、MgO含量和方解石、白云石含量变化特征,定量计算了这些取样点悬移质泥沙的CO2总碳汇能力和非永久性、永久性碳汇能力,分析了不同碳汇能力沿程变化规律及其原因。碳汇计算结果表明：寸滩—大通河段1956~2000年期间泥沙输移过程中钙镁矿物溶蚀产生的总碳汇量、非永久性和永久性碳汇量分别为2572万t/a、1700万t/a和872万t/a。由于输沙量减少,寸滩站—大通站河段的总碳汇量、非永久性和永久性碳汇量2006~2019年期间较1956~2000年期间相应分别减少了1852万t、1224万t和872万t。三峡水库年均淤积量1. 145亿t,损失总碳汇量675. 6万t,相当于三峡电站减排二氧化碳8580万t的7. 9%。全球河流入海年输沙量126. 1亿t,以寸滩- 吴淞口河段碳汇功能0. 060 t/t计,总碳汇量7. 57亿t相当于全球岩石风化碳汇总量10. 56亿t CO2的71. 6%。河流泥沙输移过程中钙镁矿物溶蚀的碳汇量具有重要的作用,其溶蚀速率大于原地风化。  相似文献   

沈北煤田煤中琥珀的植物来源和稳定同位素的古环境意义     

刘帮军  田泽奇  李鸿豆  郭旭  赵巧静  石志祥  郭文牧  张宁  Achim BECHTEL  Maksim G BLOKHIN  孙玉壮  赵存良 《地质学报》2023,97(8):2445-2458

琥珀是由古代植物代谢产生的树脂聚合物形成的化石。琥珀中的有机质保存环境稳定、封闭,能很好地记载其形成时期的古植物和古环境等信息。本次研究运用气象色谱质谱联用仪（GC-MS）和元素分析稳定同位素质谱仪（EA-IRMS）等测试方法,研究了沈北煤田煤中琥珀的有机地球化学组成、稳定同位素和化合物单体碳同位素特征。结果表明,琥珀中的饱和烃以二萜化合物为主（占73.45%）,芳香烃以松香烷型化合物为主（56.17%）;高含量的贝壳杉烷、雪松烷、扁枝烷和松香烷型化合物指示琥珀来源于松柏类植物,且以柏科植物为主。沈北琥珀的δ13C值为-22.8‰ ~ -21.2‰,与同时期其他地区琥珀的δ13C值相似;氢同位素变化范围较小（-297.2‰ ~ -276.0‰）,氧同位素值为17.4‰ ~ 31.6‰。琥珀的稳定同位素组成（碳、氢和氧）进一步证明琥珀来源于裸子植物。琥珀的δ13C值主要与其形成时的全球气温变化和大气组成有关。沈北琥珀的氢和氧同位素组成主要受植物种类（松柏类）以及植物生长的局部气温和降水条件有关。琥珀稳定碳同位素有望成为研究古气候和古大气组成的良好载体,琥珀的氢和氧同位素可以反映形成时期的古环境条件,但仍需进一步深入研究。  相似文献   

准噶尔盆地西北缘车排子凸起原油类型与油源     

刘得光  倪云燕  陈建平  李二庭  姚立邈  张枝焕  王绪龙  戴金星 《地质学报》2023,97(5):1576-1597

准噶尔盆地西北缘南部红车断裂带- 车排子凸起油气藏众多,原油物理化学性质和地球化学特征十分复杂,原油类型及其来源长期存在很大争议。本文在准噶尔盆地不同时代烃源岩生成原油典型地球化学特征与主要油源判识指标归纳总结的基础上,对红车断裂带- 车排子凸起原油地球化学特征和来源进行系统分析研究,将该区域原油分为五类,其中三类原油分别来源于二叠系湖相烃源岩、中—下侏罗统煤系烃源岩、古近系安集海河组湖相烃源岩,另外两类为混合原油,分别为来源于二叠系湖相烃源岩的生物降解稠油与中—下侏罗统煤系烃源岩生成的正常原油和古近系湖相烃源岩生成的正常原油的混合原油。红车断裂带石炭系—白垩系油藏原油主要来源于沙湾凹陷二叠系湖相烃源岩,车排子凸起东北部春风油田稠油来源于沙湾凹陷二叠系湖相烃源岩;车排子凸起东侧- 红车断裂带西侧新近系沙湾组油藏轻质原油来源于四棵树凹陷古近系湖相烃源岩;车排子凸起中部春光油田白垩系—古近系油藏稠油为二叠系来源稠油和侏罗系正常原油的混合原油,新近系沙湾组油藏稠油为二叠系来源稠油与新近系正常原油的混合原油;车排子凸起西部石炭系—古近系油藏轻质原油来源于四棵树凹陷中—下侏罗统煤系烃源岩,而新近系沙湾组油藏轻质原油来源于四棵树凹陷古近系湖相烃源岩。本文对准噶尔盆地西北缘南部地区油气藏成藏研究及区域油气勘探决策具有重要参考作用。  相似文献   

Latest Devonian to earliest Carboniferous conodont and carbon isotope stratigraphy of a shallow‐water sequence in South China     

Wenkun Qie  Xiang‐Dong Wang  Xionghua Zhang  Wenting Ji  Ethan L. Grossman  Xing Huang  Jiangsi Liu  Genming Luo 《Geological Journal》2016,51(6):915-935

To improve regional and intercontinental correlation of the uppermost Devonian–lowermost Carboniferous, we examined the conodont faunas and carbon isotopic records of the Tangbagou Formation in the Qilinzhai section, southern Guizhou, South China. The Tangbagou Formation is a succession of mixed carbonate–siliciclastic rocks that accumulated on a shallow‐water platform under normal marine conditions. Seven conodont zones for shallow‐water biofacies in South China, the Cl. gilwernensis–Cl. unicornis Zone, the Po. spicatus Zone, the Si. homosimplex Zone, the Si. sinensis Zone, the Si. eurylobata Zone, the Ps. multistriatus Zone and the Po. co. porcatus Zone in ascending order, are recognized in the Tangbagou Formation. Although apparently limited in its value for global correlation, this conodont zonation is more applicable to shallow‐water biofacies in South China. Carbonate samples have yielded carbon isotopic signatures consistent with those recorded in Euroamerica sections, in particular showing four distinct characteristics: (1) the peak values of Hangenberg Carbon Isotope Excursion (HICE) during the latest Devonian, (2) a minor positive shift (P1) in the Si. homosimplex Zone during the early Tournaisian, (3) a second minor positive shift (P2) in the Si. sinensis Zone and (4) the middle Tournaisian Carbon Isotope Excursion (TICE) in the middle part of the Tangbagou Formation. The similarity in peak values (~5.5‰) and magnitude of TICE for the Qilinzhai and Belgian sections indicates that the Euro‐asia δ¹³C_carb trends may reflect the changes in global mean ocean δ¹³C_DIC, rather than having been overprinted by local carbon cycling. Integration of conodont biostratigraphy and δ¹³C stratigraphy provides a powerful tool for stratigraphic correlation. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献